Some of the Gmail users are having multiple accounts, and also they are wished to have multiple login to chat through the same gtalk client.  To attain this feature do some following steps:

Note: If you installed the gtalk client in the default folder, then its more easier to make this feature enabled.Right Click on the Desktop
Select New
Select Shortcut
Paste this into the text box “c:\program files\google\google talk\googletalk.exe” /nomutex

Click Next, and name it whatever: Gtalk Multiple Login, etc.
Click OK until you are done.
Note: Don’t forget to Remove the .exe in the name (if your display file extension mode is off)

So enjoy chat with different Gmail accounts.

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